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Guide · Buyer essentials

PTFE vs PEEK vs Delrin vs Nylon: Choosing a Machinable Plastic

Compare temperature limits, friction, stiffness, moisture absorption, chemical resistance and cost to choose the right engineering plastic.

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The four polymers side by side

Typical unfilled, extruded or cast stock values. Treat them as selection guidance rather than design data: confirm the figures against the supplier's datasheet for the grade you actually buy.

PTFE

Polytetrafluoroethylene, virgin

Continuous service
Up to about +260 °C
Friction on steel
Dynamic coefficient about 0.05–0.10, the lowest here
Moisture uptake
Below 0.01 %, effectively nil
Tensile modulus
About 0.4–0.6 GPa, soft and creep-prone
Chemical resistance
Resists almost all industrial chemicals
Relative cost
High
Use it for
Seals, valve seats, gaskets, chute and tank liners

PEEK

Polyetheretherketone, unfilled

Continuous service
About 250 °C; glass transition near 143 °C
Friction on steel
Dynamic coefficient about 0.25–0.40 unfilled and dry
Moisture uptake
About 0.1–0.5 %
Tensile modulus
About 3.6–4.0 GPa, the stiffest here
Chemical resistance
Very good; attacked by concentrated sulphuric acid
Relative cost
Highest of the four, by a wide margin
Use it for
Semiconductor fixtures, hot insulators, pump wear rings

Delrin (acetal)

POM homopolymer and copolymer

Continuous service
Up to about 100 °C
Friction on steel
Dynamic coefficient about 0.20–0.35
Moisture uptake
About 0.2 % at 50 % relative humidity
Tensile modulus
About 2.8–3.3 GPa, stiff and dimensionally stable
Chemical resistance
Good to fuels and solvents; poor to strong acids
Relative cost
Lowest to moderate; usual baseline
Use it for
Gears, rollers, spacers, insulators, precision fixtures

Nylon

PA6 and PA66, cast or extruded

Continuous service
Up to about 100 °C
Friction on steel
Dynamic coefficient about 0.25–0.40
Moisture uptake
About 2–3 % at equilibrium, more on immersion
Tensile modulus
About 3.0–3.3 GPa dry, markedly lower once conditioned
Chemical resistance
Good to oils and alkalis; poor to acids
Relative cost
Lowest
Use it for
Bushings, wear pads, pulleys, rollers, impact parts

Start here

Quick comparison

PTFE: best chemical resistance and lowest friction, service to +260 °C, but soft and prone to creep.

PEEK: highest strength and temperature resistance (about 250 °C continuous), excellent chemical resistance, and the highest cost.

Delrin (acetal): stiff, dimensionally stable and low friction with very low moisture uptake, good to about 100 °C. Usually the best value for precision parts.

Nylon: tough and wear resistant, low cost, but it absorbs moisture, so dimensions change.

  1. 01 / 04

    When to choose PTFE

    Seals, valve seats, gaskets and liners in aggressive chemicals or at extreme temperatures. Consider glass- or carbon-filled PTFE to reduce creep.

  2. 02 / 04

    When to choose PEEK

    Semiconductor fixtures, high-temperature insulators, pump wear rings and anywhere a plastic must replace metal under load and heat.

    Caliper inspection of a PTFE seal — illustrative machining image
    Illustrative machining and inspection imagery.
  3. 03 / 04

    When to choose Delrin

    Gears, rollers, insulators, spacers and precision fixtures where you need tight tolerances at a moderate price.

    Machined parts separated in export foam packaging — illustrative machining image
    Illustrative machining and inspection imagery.
  4. 04 / 04

    When to choose Nylon

    Bushings, wear pads, pulleys and rollers where toughness and cost matter more than tight tolerances.

PTFE against PEEK, where both survive the temperature

Above roughly 100 °C the choice narrows to these two, and they fail in opposite ways. PTFE gives up strength to gain chemical resistance and slip; PEEK gives up slip and cost to keep load capacity.

CriterionPTFE

Chemical and friction first

PEEK

Load and stiffness first

Continuous service temperatureUp to about +260 °CAbout 250 °C continuous
Behaviour under sustained loadCreeps and cold-flows; not suitable for a loaded press fitHolds dimension under load; can replace metal in many fittings
Tensile modulusAbout 0.4–0.6 GPaAbout 3.6–4.0 GPa, roughly seven times stiffer
Friction and dry runningLowest friction of any common polymer, runs dryModerate friction unfilled; bearing grades use PTFE and carbon fillers
Chemical attackEssentially inert to industrial chemicalsVery good, but attacked by concentrated sulphuric acid
Machining behaviourSoft and gummy; sharp tooling, light cuts, easily distorted when clampedMachines cleanly; benefits from annealed stock and stress relief on tight parts
Achievable toleranceLoose; expect relaxation after machiningTightest of the four polymers here
Relative costHighHighest

Filled PTFE, typically 15–25 % glass or carbon, reduces creep and wear sharply while keeping most of the chemical resistance. It is often the right answer where virgin PTFE deforms and PEEK is unaffordable.

The figures that decide the selection

Four numbers separate these materials more reliably than any datasheet summary.

+260 °C
PTFE continuous service limit

PEEK is close behind at roughly 250 °C; acetal and nylon stop near 100 °C.

0.05–0.10
PTFE dynamic friction on steel

Three to six times lower than PEEK, acetal or nylon unfilled.

2–3 %
Nylon moisture uptake at equilibrium

Against about 0.2 % for acetal and under 0.01 % for PTFE, which is why nylon moves.

~4 GPa
PEEK tensile modulus

Roughly seven times PTFE, and the reason PEEK replaces metal under load.

Specifying a machined plastic part

Polymer parts are quoted from the same drawings as metal parts, but they do not behave like metal. These are the entries that make a plastic drawing buildable.

State these on the drawing

  • The polymer and the grade, not just the family: PTFE virgin or 25 % glass filled, POM-H or POM-C, PA6 cast or PA66 extruded
  • Operating temperature range, and the media or chemicals the part will see
  • Which two or three dimensions are functional; general tolerances to ISO 2768-m elsewhere
  • Stock form where it matters, since rod, tube and plate relax differently after machining
  • Whether a stress-relief or annealing step is required between roughing and finishing
  • For nylon, the humidity at which the dimensions apply, and any clearance allowed for swelling
  • Surface finish only where it has a function, such as a sealing face or a bearing bore

Avoid these specifications

  • PTFE in a loaded press fit or a threaded joint carrying torque; it will cold-flow
  • Nylon on an ISO 286 fit in humid or wet service, where moisture growth moves the dimension off tolerance
  • Metal-grade fits such as h6 on long plastic diameters, with no relaxation allowance
  • PEEK chosen for chemical resistance alone, where filled PTFE or acetal would do the same job far cheaper
  • Acetal or nylon above roughly 100 °C continuous, or acetal in strong acids
  • Thin unsupported webs and deep narrow pockets, which spring away from the cutter
  • Requesting a certified hardness or material test in house; material testing is not done on site

The short answer

Which machinable plastic should you choose?

Start with acetal (Delrin) and only move away from it for a reason. Acetal is stiff, dimensionally stable, low friction and the cheapest to hold a tolerance in. Switch to PTFE when chemical attack or friction governs and the part carries almost no load; to PEEK when the part must hold strength above roughly 150 °C or replace a metal component; and to nylon only where toughness and price matter more than dimensional accuracy.

  • Acetal: gears, rollers, spacers, precision fixtures to about 100 °C
  • PTFE: seals, valve seats, gaskets, liners; use filled grades to curb creep
  • PEEK: hot insulators, wear rings, semiconductor fixtures; highest cost
  • Nylon: bushings, wear pads and pulleys; allow for 2–3 % moisture uptake
  • Machined in Pune on CNC turning centres and a 3-axis VMC from your drawing and STEP model

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